by Intuit » Feb 21st, '09, 11:29
Tea processing changes leaf cell wall structure, making it porous. The first steps bruise leaves to cause release of oils and degradative enzymes. Additional steps, cause oxygen to be added (oxidation) when heat is applied. This changes plant cell structures related to flavor and aroma, including chlorophylls, polyphenols and flavenols, oxidizing them, making them more water soluble. Additional processing steps (oolongs and black teas) cause these structures to cross-react at the points where oxygen was added, forming new and larger compounds that add complexity to flavor and aroma and also decrease volatility, prolonging flavor release at the expense of aroma. Final steps dessicate leaves, making them less prone to lose these flavor and aroma compounds and stabilizing the leaf against microbial and natural oxidative decay, to give the final tea product 'shelf life' of 6 months to 2 years.
The more porous the leaf (oxidation and fermentation steps), the faster the flavor components leak out. Tea preparation techniques differ, to take advantage of chemistry dictated by the tea type, variety, and processing steps used.
For a black tea, bitterness and astringency - two different flavor characteristics, are determined by compounds that leach out sequentially over the step duration:
Caffeine and related stimulants - Bitter (also called briskness)
Theaflavins (secondary reactions) - Astringent
Thearubigin (ditto) - Ashy and slight astringent
Polyphenols - Astringent
The sweet compounds are related to cell wall sugars, amino acids, and semi-volatile oils that are also classed as 'fruity' and 'floral'.
The sugars elute first, if they haven't been heavily oxidized (black vs green teas), then amino acids are released (ditto on the oxidation), then the sweet oils are released, sometimes observed as a sweet 'finish'.
Overbrewing/steeping causes excessive release of astringent components, while heavily processed teas with highly porous leaves and varietals with naturally higher caffeine levels, will have an early release of bitterness.
The bitter quality can be removed by a short 'wash' step, of 20-30 seconds, before brewing leaves - decaffeination.